Well-Oiled  
for Marine Engineers

Facts and comments about engines, their lubrication and efficient running of ship.

Water contamination

Water is often overlooked as a primary cause of component failure. Yet, water contamination can reduce bearing life by as much as 90%.

Not only does water have a direct harmful effect on machine components, but it also plays a direct role in the ageing rate of lubricating oils. The presence of water in lubricating oil can cause the progress of oxidation to increase tenfold, resulting in premature ageing of the oil (particularly in the presence of catalytic metals such as copper, lead and tin).

There are a number of onboard test devices that can help engineers identify and determine the levels of water contamination from an oil sample. Guidelines of minimum/maximum limits and suggested action plans are useful references to help engineers decide on the appropriate course of action.

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Should you replenish oil additives?

Over a period of time oil additives are depleted, performing the function for which they were formulated. They are degraded by hydrolysis, mechanical shearing, condensation settling, water washing, particle scrubbing, etc.

The rate of depletion or degradation depends upon the application and the environment. In particular, heat, pressure, shear rate, fuel sulphur, soot, dirt, water, aeration and the presence of catalytic metals (copper, iron, etc.) affect the rate of depletion.

Everytime you top-up a system, you are in effect replenishing additives. Likewise, one can perform a partial drain and replacement (often referred to as bleed and feed). A bleed and feed can work if the base oil is not degraded. If the base oil has been degraded, adding new oil is analogous to sending a healthy person into a room full of sick people with the hope that his or her good health will be contagious - it doesn't work that way. The additives in the new oil might be compromised within the first hours of use, leaving you right back where you started.

Should you perhaps reclaim or recycle the oil?

It is important to understand the difference between oil recycling and oil reclamation, so let's start with an explanation of each:

(a) Oil Recycling : any treatment that completely restores the original lubricating properties of the oil (re-refining). In this context, recycled oil can be put back in service as a formulation differing from the original, and/or possibly in an application with less stringent lubrication requirements. For example, heavily oxidised oil, admixed formulations and some chemically contaminated oils cannot economically be reclaimed. However, they can be recycled and rendered useful again for the same application by re-refining them, stripping out all additives and re-additizing them. Re-refining is not a simple process nor is it as economical as reclamation.

Common used oil recycling methods:

  • Re-refining of used oil, to use as a base stock for lubricating oil. This recycling option applies physical and chemical treatments to the used oil to remove impurities until the re-refined oil is of as high a quality as the virgin oil product. In addition, re-refining takes from 50 to 85% less energy than refining virgin oil into lubricating oil. One disadvantage of re-refining is that it is more complicated and expensive than other recycling options. However, re-refining used oil into lubricating oil is easier and less expensive than re-refining crude oil into lubricating oil, and the costs associated with re-refining used oil usually can be recaptured when the lubricating oil is sold. A second disadvantage is that only a few re-refining facilities are currently in operation worldwide.
  • Slipstreaming used oil, to use as a base stock for other petroleum products. This method is done by introducing small amounts (approximately 1% of the feedstock material) of used oil into the virgin oil refining process. The refining process then removes all contaminants in the used oil that will affect the quality of the resulting petroleum product. The major advantage of slipstreaming is that the lubrication value of the used oil can be utilized without complicated processing methods. In addition, slipstreaming poses no greater environmental risk than refining virgin oil. Lack of availability is the main disadvantage, however, it is expected that slipstreaming and re-refining may become more available in the future.
  • Processing used oil, to burn for heat. This method involves treating used oil so that it will make a better fuel. Processing used oil is a widespread industry (there are almost 200 processors in the USA alone). Also, processing improves the burning quality of used oil, allowing it to be burned by a greater number of burning facilities.
  • Direct burning of used oil for heat. This method burns used oil without processing it first to remove contaminants. The major advantage is that it allows the heat value of used oil to be utilized without the expense of processing the used oil before burning. Facilities that generate large amounts of used oil (eg power generation) find this method quite attractive.

(b) Oil Reclamation : the act of salvaging, recovering or reclaiming of oil involving the removal of contaminants and degradation products. For example, dirty, wet oil with a low additive content may be a candidate for reclamation because the dirt and water can be removed. Through the guidance of an expert in formulations (or from the oil supplier), the additive package may be refortified. The oil can then be placed back into the same service for which it was originally formulated, in a condition suitable for continued service. In most cases, performance analysis on reclaimed oils is recommended to confirm “like new” or “fit for service” condition.

It is usually futile to attempt to recondition lubricants that are showing signs of oxidation. This is evidenced by rising Acid Number, increased Viscosity, and darkened oil colour. When in doubt, confirm by laboratory analysis whether a used lubricant or hydraulic fluid is a candidate for reclamation.

Casual addition of additives into a formulated oil, without the guidance of detailed oil sample analysis and the advice of an expert, can be dangerous and should be avoided. Lubricant suppliers discourage such practices. This is more so when the equipment is still under warrantee, or it has a very high cost of replacement.

36% of all bearings fail prematurely due to incorrect lubrication

Choosing the right bearing grease for the right application is critical to bearing performance. Conditions such as load, speed, temperature and environment determine the type of grease needed for the application. Injecting the correct quantity of grease is also of paramount importance, since over-greasing can contribute to machine downtime and early failure.

Fitting an automatic grease lubricator on pumps, fans, cranes etc, would ensure long term lubrication at the point of application. Ideal for providing safe, clean, cost effective lubrication in difficult to reach or restricted areas. Users are able to control the amount of grease used in each application, by setting the dispense rate on the timer of the lubricator. Grease levels can be checked through the transparent container.

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Hints and Tips

Filters are commonly classified according to absolute or nominal ratings. A filter that is classified absolute has an efficiency of 98 % or better at the specified micron size, and a filter that is classified nominal has an efficiency of between 50 % and 95 % at the specified micron size.
Hydraulic oil darkening

"After taking a sample from a hydraulic system you notice the hydraulic fluid has become darker. Concerned, you rush a sample to the oil supplier for analysis. The results of the oil analysis appear normal: Acid number, Viscosity and FTIR-Ox (oxidation) have all remained stable. A quick inspection of the hydraulic system reveals that the hydraulic valves have turned goldish in colour. What would you do?"

The goldish colour on the valves is varnish, which you would also find on all surfaces of the tank, piping, valves and the sight glasses. You are also likely to notice a change in the oil's smell. The problem is due to thermal stressing of the oil, as opposed to straight oxidation. Most likely, a valve has failed on a subsystem, forcing oil through a small orifice, causing it to overheat. Because it is a small localized hot spot in a large tank and oil cooler, the high temperature would never be detected as a rise in bulk oil temperature. The first indication of a problem would be the change in the oil’s colour.

Initially, you should confirm this with further oil analysis and if proven, drain, flush and clean the system with a solvent or an oil that is compatible with the current operating oil.

Want to know more? The fact that the acid number, viscosity or FT-IR-Ox have not changed indicate that oxidation is not taking place in the hydraulic oil. However, the golden residue on the valves is a clear sign that varnish is precipitating out of the fluid. Since varnish is composed of fluid degradation by-products, then thermal degradation is likely to be the cause of the fluid deterioration (which occurs in the absence of oxygen). Left untouched, this varnish will impact the valve's capability to function properly.

The cause of thermal degradation is heat. Two of the most common sources of extreme temperatures in a hydraulic system are (a) a hot spot caused from an external heat source in close proximity to the lube system, or (b) the implosion of entrained bubbles as the bubbles flow from the reservoir into higher pressure zones like the pumps or valves.

Three steps to address this problem:

(1) Confirm that thermal degradation is indeed the source of the problem. Ask the laboratory to provide the FT-IR curve, and instead of looking at the wavenumber region where oxidation levels are measured (1714 cm-1), look for a peak in the nitration region (1630 cm-1), to confirm it is indeed thermal degradation.

(2) Perform a root cause analysis to investigate the source of the heat in the system and determine if it is a system design flaw or if there is a solution that could be engineered to remove this heat source. If the problem appears to be entrained air, there are technologies available to remove bubbles from the hydraulic fluid to solve this problem.

(3) If thermal degradation is a result of system design, utilize a separation technology to remove the thermal degradation byproducts from the fluid, providing a permanent band-aid to the varnish formation until system redesign can be accomplished.

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